A Hollow Silicon Nanosphere/Carbon Nanotube Composite as an Anode Material for Lithium-Ion Batteries
نویسندگان
چکیده
Silicon possesses a high theoretical specific capacity and is promising high-performance anode material for lithium-ion batteries (LIBs). However, it shows poor cycling performance because of volume expansion. A hollow structure can improve Si performance, the template method one most common methods micro/nanosphere preparation. polystyrene (PS) microsphere has advantages having uniform controllable particle size, easy modification, stability, thus being an ideal preparing material. Herein, PS microspheres are used as templates to obtain silica spheres, then silicon spheres with inner pore diameter ~50 nm by magnesium thermal reduction method. Lithium-ion battery obtained using carbon nanotubes supporting (Si-CNTs). Si-CNTs exhibit excellent (1188 mAh g−1 after 200 cycles) rate capability (484 at 1 g−1). Hollow porous show great potential, providing idea solving expansion problem Si.
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ژورنال
عنوان ژورنال: Coatings
سال: 2022
ISSN: ['2079-6412']
DOI: https://doi.org/10.3390/coatings12101515